Issue 95, 2013
From the journal:

Chemical Communications

Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex†

Kazuya Arashiba,a   Shogo Kuriyama,a   Kazunari Nakajimaa  and  Yoshiaki Nishibayashi*a  

* Corresponding authors

a Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, Japan
E-mail: ynishiba@sogo.t.u-tokyo.ac.jp
Fax: +81-3-5841-1175

Abstract

A dinitrogen-bridged dimolybdenum-tetrachloride complex is prepared and reduced with Super-Hydride (LiBHEt3) to afford the corresponding dimolybdenum-dinitrogen complex together with the formation of molecular dihydrogen. This reaction proceeds via the ligand exchange of the coordinated dihydrogen generated in situ with molecular dinitrogen.

Graphical abstract: Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex

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Article information

DOI
https://doi.org/10.1039/C3CC46946H
Article type
Communication
Submitted
11 Sep 2013
Accepted
08 Oct 2013
First published
23 Oct 2013
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2013,49, 11215-11217

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Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex

K. Arashiba, S. Kuriyama, K. Nakajima and Y. Nishibayashi, Chem. Commun., 2013, 49, 11215 DOI: 10.1039/C3CC46946H

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