Issue 99, 2013
From the journal:

Chemical Communications

Solvent effects on the molecular recognition of anions†

Alireza Shokria  and  Steven R. Kass*a  

* Corresponding authors

a Department of Chemistry, University of Minnesota, Minneapolis, MN 55455, USA
E-mail: kass@umn.edu
Fax: +1-612-626-7541
Tel: +1-612-625-7513

Abstract

Anion recognition of two flexible diols in different solvents and binary mixtures were examined. Binding constants (K) in CD3CN and CDCl3 are surprisingly similar, and CD3CN–solvent mixtures led to reduced values of K that are smaller than in either pure solvent. A surprising U-shaped dependence is observed.

Graphical abstract: Solvent effects on the molecular recognition of anions

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Article information

DOI
https://doi.org/10.1039/C3CC46961A
Article type
Communication
Submitted
11 Sep 2013
Accepted
23 Oct 2013
First published
24 Oct 2013

Chem. Commun., 2013,49, 11674-11676

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Solvent effects on the molecular recognition of anions

A. Shokri and S. R. Kass, Chem. Commun., 2013, 49, 11674 DOI: 10.1039/C3CC46961A

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