Issue 99, 2013
From the journal:

Chemical Communications

Slow magnetic relaxation in radical cation tetrathiafulvalene-based lanthanide(iii) dinuclear complexes†

Fabrice Pointillart,*a   Boris Le Guennic,a   Stéphane Golhen,a   Olivier Cadora  and  Lahcène Ouahaba  

* Corresponding authors

a Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS – Université de Rennes 1, 35042, Rennes Cedex, France
E-mail: fabrice.pointillart@univ-rennes1.fr
Fax: +33 (0)2 23 23 68 40
Tel: +33 (0)2 23 23 67 52

Abstract

Lanthanide dinuclear complexes involving tetrathiafulvalene-based ligands in their radical cation form were synthesised and crystallised by a galvanostatic procedure. Dynamic magnetic measurements reveal an unprecedented slow magnetic relaxation for the Dy(III) analogue in this kind of molecular edifice.

Graphical abstract: Slow magnetic relaxation in radical cation tetrathiafulvalene-based lanthanide(iii) dinuclear complexes

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Article information

DOI
https://doi.org/10.1039/C3CC47087C
Article type
Communication
Submitted
16 Sep 2013
Accepted
17 Oct 2013
First published
18 Oct 2013

Chem. Commun., 2013,49, 11632-11634

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Slow magnetic relaxation in radical cation tetrathiafulvalene-based lanthanide(III) dinuclear complexes

F. Pointillart, B. Le Guennic, S. Golhen, O. Cador and L. Ouahab, Chem. Commun., 2013, 49, 11632 DOI: 10.1039/C3CC47087C

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