Issue 99, 2013
From the journal:

Chemical Communications

Unprecedented induced axial chirality in a molecular BODIPY dye: strongly bisignated electronic circular dichroism in the visible region†

Esther M. Sánchez-Carnerero,a   Florencio Moreno,a   Beatriz L. Maroto,a   Antonia R. Agarrabeitia,a   Jorge Bañuelos,b   Teresa Arbeloa,b   Iñigo López-Arbeloa,b   María J. Ortiz*a  and  Santiago de la Moya*a  

* Corresponding authors

a Depto. de Química Orgánica I, Facultad de CC. Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, Madrid, Spain
E-mail: santmoya@ucm.es
Fax: +34 91 394 4103
Tel: +34 91 394 5090

b Depto. de Química Física, Universidad del Pais Vasco-EHU, Apartado 644, Bilbao, Spain

Abstract

Enantiomeric bis(BODIPYs) 1a and 1b exhibit strong bisignated ECD due to the formation of a stable helical conformation with induced axial chirality, which allows efficient exciton coupling of the BODIPY chromophores in the Vis region.

Graphical abstract: Unprecedented induced axial chirality in a molecular BODIPY dye: strongly bisignated electronic circular dichroism in the visible region

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Article information

DOI
https://doi.org/10.1039/C3CC47570K
Article type
Communication
Submitted
02 Oct 2013
Accepted
21 Oct 2013
First published
22 Oct 2013

Chem. Commun., 2013,49, 11641-11643

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Unprecedented induced axial chirality in a molecular BODIPY dye: strongly bisignated electronic circular dichroism in the visible region

E. M. Sánchez-Carnerero, F. Moreno, B. L. Maroto, A. R. Agarrabeitia, J. Bañuelos, T. Arbeloa, I. López-Arbeloa, M. J. Ortiz and S. D. L. Moya, Chem. Commun., 2013, 49, 11641 DOI: 10.1039/C3CC47570K

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