The molar polarisability and molar volume for 71 ionic liquids were extracted from 157 measurements of their refractive index and density, which were then further deconstructed into atomic contributions by means of a Designed Regression analysis. Using this approach, the density and refractive index for any chosen ionic liquid with alkyl-substituted imidazolium cations can be predicted in good agreement with experimental data.
K. Bica, M. Deetlefs, C. Schröder and K. R. Seddon, Phys. Chem. Chem. Phys., 2013, 15, 2703 DOI: 10.1039/C3CP43867H
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