Issue 12, 2013
From the journal:

Catalysis Science & Technology

Cyclopentadienyl N-heterocyclic carbene–nickel complexes as efficient pre-catalysts for the hydrosilylation of imines†

Linus P. Bheeter,a   Mickaël Henrion,b   Michael J. Chetcuti,b   Christophe Darcel,a   Vincent Ritleng*bc  and  Jean-Baptiste Sortais*a  

* Corresponding authors

a “Institut des Sciences Chimiques de Rennes”, UMR 6226 CNRS, Université de Rennes 1, Equipe “Organometallics: Materials and Catalysis”, Centre of Catalysis and Green Chemistry, Campus de Beaulieu, Bat 10C, Avenue du Général Leclerc, 35042 Rennes Cedex, France
E-mail: jean-baptiste.sortais@univ-rennes1.fr
Fax: +33 2 2323 6939
Tel: +33 2 2323 6288

b Laboratoire de Chimie Organométallique Appliquée, UMR 7509 CNRS, Université de Strasbourg, Ecole européenne de Chimie, Polymères et Matériaux, 25 rue Becquerel, 67087 Strasbourg, France
E-mail: vritleng@unistra.fr
Tel: + 33 3 6885 2797

c USIAS, Institut d’Etudes Avancées de l’Université de Strasbourg, 5 allée du Général Rouvillois, 67083 Strasbourg, France

Abstract

The in situ generated nickel hydride complex, [Ni(Mes2NHC)HCp], and its cationic analogue, [Ni(Mes2NHC)(NCMe)Cp](PF6), are efficient and chemoselective pre-catalysts for the hydrosilylation of both aldimines and ketimines under mild conditions.

Graphical abstract: Cyclopentadienyl N-heterocyclic carbene–nickel complexes as efficient pre-catalysts for the hydrosilylation of imines

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Article information

DOI
https://doi.org/10.1039/C3CY00514C
Article type
Communication
Submitted
17 Jul 2013
Accepted
10 Sep 2013
First published
10 Sep 2013

Catal. Sci. Technol., 2013,3, 3111-3116

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Cyclopentadienyl N-heterocyclic carbene–nickel complexes as efficient pre-catalysts for the hydrosilylation of imines

L. P. Bheeter, M. Henrion, M. J. Chetcuti, C. Darcel, V. Ritleng and J. Sortais, Catal. Sci. Technol., 2013, 3, 3111 DOI: 10.1039/C3CY00514C

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