Issue 2, 2013

An open-framework rutile-type magnesium isonicotinate and its structural analogue with an anatase topology

Abstract

Two new photoluminescent magnesium-based coordination polymers, Mg(int)2·H2O (1) and Mg(nt)2 (2), were synthesized under solvothermal conditions. Structural analyses reveal that they have different 3,6-connected frameworks with rutile- and anatase-type topologies, respectively. Compound 1 remains stable after the removal of its guest molecules and it exhibits weak ferroelectric behavior.

Graphical abstract: An open-framework rutile-type magnesium isonicotinate and its structural analogue with an anatase topology

Supplementary files

Article information

Article type
Communication
Submitted
28 Jun 2012
Accepted
06 Nov 2012
First published
07 Nov 2012

Dalton Trans., 2013,42, 368-371

An open-framework rutile-type magnesium isonicotinate and its structural analogue with an anatase topology

T. Liu, D. Luo, D. Xu, H. Zeng and Z. Lin, Dalton Trans., 2013, 42, 368 DOI: 10.1039/C2DT31394D

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