Issue 5, 2013
From the journal:

Dalton Transactions

Palladium ketonyl carboxylate complexes – potential models of polynuclear intermediates in olefin oxidation: formation and X-ray structure of Pd6(μ-Cl)2+x(μ-CF3CO2)4(μ,κ2-CH2C(O)CMe3)6−x (x = 0, 2)†

Oleg N. Shishilov,*a   Roman E. Podobedov,a   Yaroslavna N. Rezinkova,a   Andrei V. Churakova  and  Inessa A. Efimenkoa  

* Corresponding authors

a Leninsky pr., 31, Moscow, Russia
E-mail: oshishilov@gmail.com
Fax: +007 495 9541279
Tel: +007 495 9554844

Abstract

Reactions of Pd4(NO)4(CF3CO2)4 with olefins were studied, this Pd-cluster was shown to promote the oxidation of olefins into ketones, which were found as ketonyl ligands in complex products of the reaction; 6-nuclear palladium clusters with carboxylate and ketonyl ligands Pd6(μ-Cl)x(μ-CF3CO2)4(μ,κ2-CH2C(O)CMe3)6−x were characterized by XRD analysis.

Graphical abstract: Palladium ketonyl carboxylate complexes – potential models of polynuclear intermediates in olefin oxidation: formation and X-ray structure of Pd6(μ-Cl)2+x(μ-CF3CO2)4(μ,κ2-CH2C(O)CMe3)6−x (x = 0, 2)

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Article information

DOI
https://doi.org/10.1039/C2DT31824E
Article type
Communication
Submitted
10 Aug 2012
Accepted
21 Nov 2012
First published
22 Nov 2012

Dalton Trans., 2013,42, 1338-1341

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Palladium ketonyl carboxylate complexes – potential models of polynuclear intermediates in olefin oxidation: formation and X-ray structure of Pd6(μ-Cl)2+x(μ-CF3CO2)4(μ,κ2-CH2C(O)CMe3)6−x (x = 0, 2)

O. N. Shishilov, R. E. Podobedov, Y. N. Rezinkova, A. V. Churakov and I. A. Efimenko, Dalton Trans., 2013, 42, 1338 DOI: 10.1039/C2DT31824E

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