Serendipitous anion-templated self-assembly of a sandwich-like Ag20S10 macrocycle-based high-nuclearity luminescent nanocluster

Kun Zhou; Xin-Long Wang; Chao Qin; Hai-Ning Wang; Guang-Sheng Yang; Yan-Qing Jiao; Peng Huang; Kui-Zhan Shao; Zhong-Min Su

doi:10.1039/C2DT32145A

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Serendipitous anion-templated self-assembly of a sandwich-like Ag₂₀S₁₀macrocycle-based high-nuclearity luminescent nanocluster†

Kun Zhou,^a Xin-Long Wang,^a Chao Qin,*^a Hai-Ning Wang,^a Guang-Sheng Yang,^a Yan-Qing Jiao,^a Peng Huang,^a Kui-Zhan Shao^a and Zhong-Min Su*^a

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* Corresponding authors

^a Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China
E-mail: zmsu@nenu.edu.cn, qinc703@nenu.edu.cn
Fax: +860431-85684009
Tel: +860431-85099108

Abstract

The first macrocycle-based high-nuclearity nanocluster [Ag₂₀(S^tBu)₁₀(CF₃COO)₂]⁸⁺ in complex 1, with a sandwich-like structure constructed by bilevel inversion Ag₅S₅ pentagrams and an interlayer Ag₁₀ ring, has been obtained. Structure analysis indicates that Cl⁻ acts as an anion template to direct the formation of 1. In addition, the photoluminescent property of complex 1 is also investigated.

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Article information

DOI: https://doi.org/10.1039/C2DT32145A
Article type: Communication
Submitted: 17 Sep 2012
Accepted: 11 Nov 2012
First published: 15 Nov 2012

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Dalton Trans., 2013,42, 1352-1355

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Serendipitous anion-templated self-assembly of a sandwich-like Ag₂₀S₁₀ macrocycle-based high-nuclearity luminescent nanocluster

K. Zhou, X. Wang, C. Qin, H. Wang, G. Yang, Y. Jiao, P. Huang, K. Shao and Z. Su, Dalton Trans., 2013, 42, 1352 DOI: 10.1039/C2DT32145A

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