Issue 2, 2013

Two new scorpionate oxomolybdenum(vi)–poly(pyrazolyl)borate complexes: synthesis, structure, and catalytic performance in the oxidation of cyclohexane

Abstract

Two new oxomolybdenum(VI) complexes [(TpMoO2)2(μ-O)]·H2O (1) and (Tp4-IMoO2)2(μ-O) (2) were synthesized and characterized by elemental analysis, IR spectra, UV-Vis spectroscopy, powder X-ray diffraction, single-crystal X-ray diffraction and thermogravimetric analyses (TG). In addition, the catalytic performances of complexes 1 and 2 were studied firstly on the oxidation reaction of cyclohexane at room temperature.

Graphical abstract: Two new scorpionate oxomolybdenum(vi)–poly(pyrazolyl)borate complexes: synthesis, structure, and catalytic performance in the oxidation of cyclohexane

Supplementary files

Article information

Article type
Communication
Submitted
06 Aug 2012
Accepted
03 Oct 2012
First published
04 Oct 2012

Dalton Trans., 2013,42, 359-363

Two new scorpionate oxomolybdenum(VI)–poly(pyrazolyl)borate complexes: synthesis, structure, and catalytic performance in the oxidation of cyclohexane

N. Xing, H. Shan, X. Tian, Q. Yao, L. Xu, Y. Xing and Z. Shi, Dalton Trans., 2013, 42, 359 DOI: 10.1039/C2DT32184J

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