An unusual seven-connected lead borate constructed by different cluster building units of {B6} and {Pb6}

Han-Rui Tian; Wen-Hua Wang; Xiao-Ping Zhang; Yun-Long Feng; Jian-Wen Cheng

doi:10.1039/C2DT32364H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

An unusual seven-connected lead borate constructed by different cluster building units of {B₆} and {Pb₆}†

Han-Rui Tian,^a Wen-Hua Wang,^a Xiao-Ping Zhang,^a Yun-Long Feng^a and Jian-Wen Cheng*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang, P.R. China
E-mail: jwcheng@zjnu.cn

Abstract

A new 3D lead borate Pb₆B₆O₁₄(OH)₂(H₂O), built by different cluster building units of B₆O₁₄(OH) {B₆} and Pb₆O₅(OH) {Pb₆}, has been obtained under mild hydrothermal conditions. Each {B₆} cluster is linked with seven {Pb₆} clusters and vice versa that give rise to the first 7-connected lead borate network.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C2DT32364H
Article type: Communication
Submitted: 06 Oct 2012
Accepted: 11 Nov 2012
First published: 15 Nov 2012

Download Citation

Dalton Trans., 2013,42, 894-897

Permissions

Request permissions

An unusual seven-connected lead borate constructed by different cluster building units of {B₆} and {Pb₆}

H. Tian, W. Wang, X. Zhang, Y. Feng and J. Cheng, Dalton Trans., 2013, 42, 894 DOI: 10.1039/C2DT32364H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions