Issue 5, 2013
From the journal:

Dalton Transactions

Expanding the coordination chemistry of donor-stabilized group-14 metalenes†

Javier A. Cabeza,*a   Pablo García-Álvarez*a  and  Diego Poloa  

* Corresponding authors

a Departamento de Química Orgánica e Inorgánica-IUQOEM, Universidad de Oviedo-CSIC, E-33071 Oviedo, Spain
E-mail: jac@uniovi.es, pga@uniovi.es

Abstract

The transformation of an amidinate germylene, equipped with just one accessible lone pair of electrons on the Ge atom, into a bidentate 4-electron donor κ2Ge,N-ligand, has been achieved for the first time, opening new doors to the non-carbene-like coordination chemistry of heavier carbene analogues.

Graphical abstract: Expanding the coordination chemistry of donor-stabilized group-14 metalenes

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Article information

DOI
https://doi.org/10.1039/C2DT32654J
Article type
Communication
Submitted
02 Oct 2012
Accepted
06 Nov 2012
First published
07 Nov 2012

Dalton Trans., 2013,42, 1329-1332

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Expanding the coordination chemistry of donor-stabilized group-14 metalenes

J. A. Cabeza, P. García-Álvarez and D. Polo, Dalton Trans., 2013, 42, 1329 DOI: 10.1039/C2DT32654J

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