Issue 22, 2013

Palladium complexes with stabilized germylene and stannylene ligands

Abstract

The syntheses of novel Pd complexes with germylene and stannylene ligands are reported. [MeN(CH2CH2NC6F5)2Sn]4Pd (2) and [MeN(CH2CPh2O)(CH2CH2O)Ge]4Pd (8) were obtained by different methods including ligand substitution in (Ph3P)4Pd or by the reaction of the free corresponding germylene or stannylene with (Ph3P)2PdCl2 or Pd(OAc)2. Crystal structures of complexes 2, 8 were determined by single crystal X-ray diffraction analysis. The catalytic activity of complexes 2, 8 was examined in the Suzuki–Miyaura and Heck cross-coupling.

Graphical abstract: Palladium complexes with stabilized germylene and stannylene ligands

Supplementary files

Article information

Article type
Paper
Submitted
29 Nov 2012
Accepted
22 Jan 2013
First published
23 Jan 2013

Dalton Trans., 2013,42, 7901-7912

Palladium complexes with stabilized germylene and stannylene ligands

M. M. Kireenko, K. V. Zaitsev, Y. F. Oprunenko, A. V. Churakov, V. A. Tafeenko, S. S. Karlov and G. S. Zaitseva, Dalton Trans., 2013, 42, 7901 DOI: 10.1039/C3DT32867H

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