Issue 19, 2013
From the journal:

Dalton Transactions

Synthesis and characterization of a tetrathiafulvalene-salphen actinide complex†

Christopher Bejger,a   Yong-Hui Tian,b   Beau J. Barker,b   Kevin S. Boland,b   Brian L. Scott,b   Enrique R. Batista,*b   Stosh A. Kozimor*b  and  Jonathan L. Sessler*ac  

* Corresponding authors

a Department of Chemistry and Biochemistry and Institute for Cellular and Molecular Biology, The University of Texas at Austin, 105 E. 24th Street – Stop A5300, Austin, Texas 78712-1224, USA
E-mail: Sessler@cm.utexas.edu

b Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
E-mail: Stosh@lanl.gov, erb@lanl.gov

c Department of Chemistry, Yonsei University, Seoul 120-749, Korea

Abstract

A new tetrathiafulvalene-salphen uranyl complex has been prepared. The system was designed to study the electronic coupling between actinides and a redox active ligand framework. Theoretical and experimental methods – including DFT calculations, single crystal X-ray analysis, cyclic voltammetry, NMR and IR spectroscopies – were used to characterize this new uranyl complex.

Graphical abstract: Synthesis and characterization of a tetrathiafulvalene-salphen actinide complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3DT50698C
Article type
Communication
Submitted
14 Mar 2013
Accepted
15 Mar 2013
First published
09 Apr 2013

Dalton Trans., 2013,42, 6716-6719

Permissions

Request permissions

Synthesis and characterization of a tetrathiafulvalene-salphen actinide complex

C. Bejger, Y. Tian, B. J. Barker, K. S. Boland, B. L. Scott, E. R. Batista, S. A. Kozimor and J. L. Sessler, Dalton Trans., 2013, 42, 6716 DOI: 10.1039/C3DT50698C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements