Issue 1, 2013
From the journal:

Organic & Biomolecular Chemistry

Pd-catalyzed Suzuki coupling reaction of chloroalkylidene-β-lactones with LB-Phos as the ligand†

Pengbin Li,a   Bo Lü,a   Chunling Fua  and  Shengming Ma*a  

* Corresponding authors

a Laboratory of Molecular Recognition and synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China
E-mail: masm@sioc.ac.cn
Fax: +86-21-64167510

Abstract

In this paper, LB-Phos·HBF4 salt has been applied for the Pd-catalysed Suzuki coupling reactions of optically active (Z)-α-choroalkylidene-β-lactones. Aryl, vinyl, alkyl and heteroaromatic boronic acids may be coupled with optically active β-lactones affording corresponding optically active products highly selectively and efficiently.

Graphical abstract: Pd-catalyzed Suzuki coupling reaction of chloroalkylidene-β-lactones with LB-Phos as the ligand

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Article information

DOI
https://doi.org/10.1039/C2OB26365C
Article type
Paper
Submitted
16 Jul 2012
Accepted
12 Sep 2012
First published
14 Sep 2012

Org. Biomol. Chem., 2013,11, 98-109

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Pd-catalyzed Suzuki coupling reaction of chloroalkylidene-β-lactones with LB-Phos as the ligand

P. Li, B. Lü, C. Fu and S. Ma, Org. Biomol. Chem., 2013, 11, 98 DOI: 10.1039/C2OB26365C

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