Issue 24, 2013
From the journal:

Organic & Biomolecular Chemistry

Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles†

Xuan Zhang,a   Xiujuan Feng,*a   Xiaoqiang Yu,a   Ren Hea  and  Ming Bao*a  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China
E-mail: fengxiujuan@dlut.edu.cn, mingbao@dlut.edu.cn
Fax: +86-0411-84986180
Tel: +86-0411-84986181

Abstract

The palladium-catalyzed three-component reactions of benzyl halides, activated olefins, and allyltributylstannane were successfully conducted to produce the corresponding benzylallylation products in satisfactory to high yields. The benzylallylation reaction proceeded smoothly under mild conditions in the presence of palladium nanoparticles in tetrahydrofuran.

Graphical abstract: Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles

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Article information

DOI
https://doi.org/10.1039/C3OB40487K
Article type
Paper
Submitted
09 Mar 2013
Accepted
16 Apr 2013
First published
16 Apr 2013

Org. Biomol. Chem., 2013,11, 4016-4024

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Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles

X. Zhang, X. Feng, X. Yu, R. He and M. Bao, Org. Biomol. Chem., 2013, 11, 4016 DOI: 10.1039/C3OB40487K

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