Issue 37, 2013
From the journal:

Organic & Biomolecular Chemistry

Modular synthesis of all-substituted furans through oxidative carbonylation of cyclopropenes with tandem metal relay catalysis†

Chuanling Song,a   Shuli Dong,a   Lei Feng,a   Xianglong Peng,a   Mingchao Wang,a   Jianwu Wanga  and  Zhenghu Xu*a  

* Corresponding authors

a Key Lab for Colloid and Interface Chemistry of Education Ministry, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, People's Republic of China
E-mail: xuzh@sdu.edu.cn

Abstract

A modular synthesis of tetrasubstituted furan carboxylates using a tandem cycloisomerization/oxidative carbonylation sequence of cyclopropenes has been successfully developed. The Tandem Metal Relay Catalysis (TMRC) pathway accounted for the high efficiency of this transformation.

Graphical abstract: Modular synthesis of all-substituted furans through oxidative carbonylation of cyclopropenes with tandem metal relay catalysis

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Article information

DOI
https://doi.org/10.1039/C3OB41155A
Article type
Communication
Submitted
05 Jun 2013
Accepted
30 Jul 2013
First published
01 Aug 2013

Org. Biomol. Chem., 2013,11, 6258-6262

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Modular synthesis of all-substituted furans through oxidative carbonylation of cyclopropenes with tandem metal relay catalysis

C. Song, S. Dong, L. Feng, X. Peng, M. Wang, J. Wang and Z. Xu, Org. Biomol. Chem., 2013, 11, 6258 DOI: 10.1039/C3OB41155A

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