Issue 4, 2013
From the journal:

Polymer Chemistry

Trithiocarbonates prepared from iodo-functionalized RITP-polymers†

Francisco J. Enríquez-Medrano,a   Hortensia Maldonado-Textle,a   Martín Hernández-Valdez,b   Patrick Lacroix-Desmazesc  and  Ramiro Guerrero-Santos*a  

* Corresponding authors

a Centro de Investigación en Química Aplicada, Blvd. Enrique Reyna No. 140, Saltillo, Mexico
E-mail: ramirog@ciqa.mx
Tel: +52 844 4389830 ext. 1238

b Resirene S.A. de C.V. Km, 15.5 Carretera Federal Puebla-Tlaxcala, Mexico
E-mail: Martin.HValdez@resirene.com
Tel: +52 222 2233230

c Institut Charles Gerhardt, UMR 5253 CNRS/UM2/ENSCM/UM1, Ingénierie et Architectures Macromoléculaires, Ecole Nationale Supérieure de Chimie de Montpellier, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France
E-mail: patrick.lacroix-desmazes@enscm.fr
Tel: +33 467147205

Abstract

Iodo-terminated polymers (polystyrene, polybutyl acrylate and polyvinyl acetate) were synthesized by reverse iodine transfer polymerization (RITP) and then used to form homopolymeric trithiocarbonates through a coupling reaction induced by Cs2CO3/CS2. The resulting polymeric trithiocarbonates were subsequently used in RAFT polymerization to form ABA block copolymers. This coupling reaction was extended to some iodo-terminated AB diblock copolymers prepared entirely by RITP to form ABA triblock copolymers.

Graphical abstract: Trithiocarbonates prepared from iodo-functionalized RITP-polymers

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Article information

DOI
https://doi.org/10.1039/C2PY20790G
Article type
Paper
Submitted
25 Sep 2012
Accepted
23 Oct 2012
First published
24 Oct 2012

Polym. Chem., 2013,4, 978-985

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Trithiocarbonates prepared from iodo-functionalized RITP-polymers

F. J. Enríquez-Medrano, H. Maldonado-Textle, M. Hernández-Valdez, P. Lacroix-Desmazes and R. Guerrero-Santos, Polym. Chem., 2013, 4, 978 DOI: 10.1039/C2PY20790G

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