Issue 4, 2013
From the journal:

Polymer Chemistry

Copolymers featuring pentafluorophenyl ester and photolabile amine units: synthesis and application as reactive photopatterns†

Hui Zhaoa  and  Patrick Theato*ab  

* Corresponding authors

a Institute for Technical and Macromolecular Chemistry, University of Hamburg, Bundesstr.45, 20146 Hamburg, Germany
E-mail: theato@chemie.uni-hamburg.de

b World Class University (WCU) program of Chemical Convergence for Energy and Environment (C2E2), School of Chemical and Biological Engineering, College of Engineering, Seoul National University (SNU), Seoul, Korea

Abstract

Copolymers featuring pentafuorophenyl ester and o-nitrobenzyl (ONB) protected amine moieties have been prepared. Upon UV irradiation, the ONB protected amine group was released, which subsequently induced a crosslinking by a spontaneous reaction with pentafluorophenyl esters, resulting in stable, reactive patterned thin films. Remaining esters were converted with a fluorescent dye.

Graphical abstract: Copolymers featuring pentafluorophenyl ester and photolabile amine units: synthesis and application as reactive photopatterns

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Article information

DOI
https://doi.org/10.1039/C2PY21050A
Article type
Communication
Submitted
29 Nov 2012
Accepted
13 Dec 2012
First published
14 Dec 2012

Polym. Chem., 2013,4, 891-894

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Copolymers featuring pentafluorophenyl ester and photolabile amine units: synthesis and application as reactive photopatterns

H. Zhao and P. Theato, Polym. Chem., 2013, 4, 891 DOI: 10.1039/C2PY21050A

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