Issue 19, 2013
From the journal:

Polymer Chemistry

End-functional stereoregular poly(methyl methacrylate) with clickable C[double bond, length as m-dash]C bonds: facile synthesis and thiol–ene reaction†

Yasuhiro Kohsaka,a   Takashi Kurataa  and  Tatsuki Kitayama*a  

* Corresponding authors

a Department of Chemistry, Graduated School of Engineering Science, Osaka University, 1-3 Machikaneyama-cho, Toyonaka, Osaka 560-8531, Japan
E-mail: kitayama@chem.es.osaka-u.ac.jp
Fax: +81-6841-0104
Tel: +81-6-6850-6230

Abstract

Stereoregular poly(methyl methacrylate) with a clickable C[double bond, length as m-dash]C ω-end by a Michael-addition type thiol–ene reaction was synthesized through an anion terminating reaction with α-(halomethyl)acrylates. The thiol–ene click reaction at the ω-end provided various ω-functional polymers quantitatively.

Graphical abstract: End-functional stereoregular poly(methyl methacrylate) with clickable C [[double bond, length as m-dash]] C bonds: facile synthesis and thiol–ene reaction

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Article information

DOI
https://doi.org/10.1039/C3PY00799E
Article type
Communication
Submitted
19 Jun 2013
Accepted
11 Jul 2013
First published
12 Jul 2013

Polym. Chem., 2013,4, 5043-5047

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End-functional stereoregular poly(methyl methacrylate) with clickable C[double bond, length as m-dash]C bonds: facile synthesis and thiol–ene reaction

Y. Kohsaka, T. Kurata and T. Kitayama, Polym. Chem., 2013, 4, 5043 DOI: 10.1039/C3PY00799E

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