Issue 7, 2013
From the journal:

RSC Advances

Ternary phthalocyanato Hf(iv) and Zr(iv) polyoxometalate complexes†

Ivana Radivojevic,a   Kemakorn Ithisuphalap,a   Benjamin P. Burton-Pye,a   Raihan Saleh,a   Lynn C. Francesconia  and  Charles Michael Drain*ab  

* Corresponding authors

a Hunter College and Graduate Center of the City University of New York, 695 Park Avenue, New York 10065, USA
E-mail: cdrain@hunter.cuny.edu
Fax: 212-772-5332
Tel: 212-650-3791

b Rockefeller University, 1230 York Avenue, New York 10065, USA

Abstract

Ternary phthalocyanine–metal–polyoxometalate (Pc–M–POM) complexes were synthesized and characterized. Group (IV) Hf or Zr ions reside outside the plane of the macrocycle and are coordinated to both the phthalocyanine and the lacunary polyoxometalate. The metal ions mediate the electronic communication between the Pc and the POM.

Graphical abstract: Ternary phthalocyanato Hf(iv) and Zr(iv) polyoxometalate complexes

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Article information

DOI
https://doi.org/10.1039/C2RA22903J
Article type
Communication
Submitted
14 Nov 2012
Accepted
06 Dec 2012
First published
21 Dec 2012

RSC Adv., 2013,3, 2174-2177

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Ternary phthalocyanato Hf(IV) and Zr(IV) polyoxometalate complexes

I. Radivojevic, K. Ithisuphalap, B. P. Burton-Pye, R. Saleh, L. C. Francesconi and C. M. Drain, RSC Adv., 2013, 3, 2174 DOI: 10.1039/C2RA22903J

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