Issue 34, 2013
From the journal:

RSC Advances

Metal–organic framework membranes with layered structure prepared within the porous support†

Nobuo Hara,*a   Miki Yoshimune,a   Hideyuki Negishi,a   Kenji Haraya,a   Shigeki Haraa  and  Takeo Yamaguchib  

* Corresponding authors

a Research Institute for Innovation in Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan
E-mail: n-hara@aist.go.jp
Fax: +81-29-861-4457
Tel: +81-29-849-1164

b Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama 226-8503, Midori-ku, Japan

Abstract

A uniquely microstructured membrane, a metal–organic framework (MOF) layer within the porous support, was prepared by a counter-diffusion method. The MOF-based membrane prepared from the copper benzene tricarboxylate (Cu-BTC), one of the MOFs, exhibited excellent gas perm-separation properties with an ideal H2/CH4 selectivity of 153.

Graphical abstract: Metal–organic framework membranes with layered structure prepared within the porous support

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Article information

DOI
https://doi.org/10.1039/C3RA22733B
Article type
Communication
Submitted
01 Nov 2012
Accepted
21 Jun 2013
First published
24 Jun 2013

RSC Adv., 2013,3, 14233-14236

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Metal–organic framework membranes with layered structure prepared within the porous support

N. Hara, M. Yoshimune, H. Negishi, K. Haraya, S. Hara and T. Yamaguchi, RSC Adv., 2013, 3, 14233 DOI: 10.1039/C3RA22733B

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