Issue 33, 2013
From the journal:

RSC Advances

Tandem semi-hydrogenation/isomerization of propargyl alcohols to saturated carbonyl analogues by dodecanethiolate-capped palladium nanoparticle catalysts†

Diego J. Gavia,‡a   Jordan Koeppen,‡a   Elham Sadeghmoghaddama  and  Young-Seok Shon*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, California State University, Long Beach. 1250 Bellflower Blvd., Long Beach, CA 90840-9507, United States
E-mail: ys.shon@csulb.edu
Fax: (562) 985-8557
Tel: (562) 985-4466

Abstract

The efficient one-pot conversion of propargyl alcohols to their saturated carbonyl analogues is carried out for the first time using metal nanoparticle catalysts, dodecanethiolate-capped Pd nanoparticles. Kinetic studies reveal that the reaction progresses through a semi-hydrogenation intermediate (allyl alcohols) followed by isomerization to carbonyls.

Graphical abstract: Tandem semi-hydrogenation/isomerization of propargyl alcohols to saturated carbonyl analogues by dodecanethiolate-capped palladium nanoparticle catalysts

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Article information

DOI
https://doi.org/10.1039/C3RA42119H
Article type
Communication
Submitted
29 Apr 2013
Accepted
07 Jun 2013
First published
07 Jun 2013

RSC Adv., 2013,3, 13642-13645

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Tandem semi-hydrogenation/isomerization of propargyl alcohols to saturated carbonyl analogues by dodecanethiolate-capped palladium nanoparticle catalysts

D. J. Gavia, J. Koeppen, E. Sadeghmoghaddam and Y. Shon, RSC Adv., 2013, 3, 13642 DOI: 10.1039/C3RA42119H

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