Issue 43, 2013
From the journal:

RSC Advances

Oxidative transformation of cyclic ethers/amines to lactones/lactams using a DIB/TBHP protocol†

Yi Zhao,a   Jascelyn Qian Lin Ang,a   Angela Wan Ting Nga  and  Ying-Yeung Yeung*a  

* Corresponding authors

a Department of Chemistry, NUS, 3 Science Drive 3, Singapore 117543
E-mail: chmyyy@nus.edu.sg
Fax: +65-6779-1691
Tel: +65-6516-7760

Abstract

A novel C–H oxidation of cyclic ethers and amines to the corresponding lactones and lactams was developed using a DIB/TBHP protocol. The reaction is mild and no metallic reagent is involved. In addition, study shows that the electronic properties of the substituents could affect the selectivity of oxidation.

Graphical abstract: Oxidative transformation of cyclic ethers/amines to lactones/lactams using a DIB/TBHP protocol

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Article information

DOI
https://doi.org/10.1039/C3RA44184A
Article type
Communication
Submitted
06 Aug 2013
Accepted
13 Aug 2013
First published
14 Aug 2013

RSC Adv., 2013,3, 19765-19768

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Oxidative transformation of cyclic ethers/amines to lactones/lactams using a DIB/TBHP protocol

Y. Zhao, J. Q. L. Ang, A. W. T. Ng and Y. Yeung, RSC Adv., 2013, 3, 19765 DOI: 10.1039/C3RA44184A

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