Issue 48, 2013
From the journal:

RSC Advances

Efficient ipso-nitration of arylboronic acids with iron nitrate as the nitro source†

Min Jiang,ab   Haijun Yang,*ab   Yong Li,ab   Zhiying Jiab  and  Hua Fub  

* Corresponding authors

a Beijing Key Laboratory for Analytical Methods and Instrumentation, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China
E-mail: cyhj@ tsinghua.edu.cn
Fax: +86-10-62788971

b Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

Abstract

A novel, simple and efficient ipso-nitration of arylboronic acids with iron nitrate has been developed. The protocol uses readily available arylboronic acids as the starting materials, inexpensive iron nitrate (0.5 equiv.) as the nitro source without addition of an additive, and the corresponding nitroarenes were obtained in good to excellent yields.

Graphical abstract: Efficient ipso-nitration of arylboronic acids with iron nitrate as the nitro source

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Article information

DOI
https://doi.org/10.1039/C3RA45118F
Article type
Communication
Submitted
14 Sep 2013
Accepted
15 Oct 2013
First published
22 Oct 2013

RSC Adv., 2013,3, 25602-25604

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Efficient ipso-nitration of arylboronic acids with iron nitrate as the nitro source

M. Jiang, H. Yang, Y. Li, Z. Jia and H. Fu, RSC Adv., 2013, 3, 25602 DOI: 10.1039/C3RA45118F

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