Issue 31, 2013

Molecular orientation dynamics on the structural rheology in diblock copolymers

Abstract

We formulate a viscoelastic theory of micro-phase separated structures in diblock copolymers in which the local composition is coupled with the molecular orientation. The linear viscoelastic response is investigated for aligned lamellar structures. Three kinds of complex moduli and viscosities characterizing an incompressible lamellar structure are obtained up to the leading order of the coupling.

Graphical abstract: Molecular orientation dynamics on the structural rheology in diblock copolymers

Article information

Article type
Paper
Submitted
06 Jan 2013
Accepted
30 May 2013
First published
25 Jun 2013

Soft Matter, 2013,9, 7479-7488

Molecular orientation dynamics on the structural rheology in diblock copolymers

S. Yabunaka and T. Ohta, Soft Matter, 2013, 9, 7479 DOI: 10.1039/C3SM00040K

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