Issue 48, 2013
From the journal:

Journal of Materials Chemistry A

A rechargeable Si–air solid state oxygen shuttle battery incorporating an oxide ion conductor†

Atsushi Inoishi,a   Takaaki Sakai,ab   Young-Wan Ju,a   Shintaro Idaac  and  Tatsumi Ishihara*ac  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

b Center for Molecular Systems, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

c International Institute for Carbon Neutral Energy (WPI-I2CNER), Kyushu University, Japan
E-mail: ishihara@cstf.kyushu-u.ac.jp
Fax: +81-92-802-2871
Tel: +81-92-802-2868

Abstract

Herein, we report a new type of Si–air rechargeable battery incorporating an oxide ion conducting electrolyte, based on the oxygen shuttle concept. A cell designed in this manner and employing Ca stabilized ZrO2 exhibited stable charge–discharge over 20 cycles at 1073 K and achieved a discharge capacity of approximately 600 mA h gSi−1.

Graphical abstract: A rechargeable Si–air solid state oxygen shuttle battery incorporating an oxide ion conductor

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Article information

DOI
https://doi.org/10.1039/C3TA14023G
Article type
Communication
Submitted
07 Oct 2013
Accepted
21 Oct 2013
First published
22 Oct 2013

J. Mater. Chem. A, 2013,1, 15212-15215

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A rechargeable Si–air solid state oxygen shuttle battery incorporating an oxide ion conductor

A. Inoishi, T. Sakai, Y. Ju, S. Ida and T. Ishihara, J. Mater. Chem. A, 2013, 1, 15212 DOI: 10.1039/C3TA14023G

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