Issue 23, 2013

Bioorganic hybrid OMS by straightforward grafting of trialkoxysilyl peptides

Abstract

A novel strategy for the synthesis of peptide–bioorganic hybrid silica materials is reported. It relies on the design of hybrid peptides bearing a trialkoxysilane group. These reactive monomers are covalently attached to silica without requiring any prior surface modification. As an example, a bioorganic–inorganic OMS aldolisation catalyst is prepared using the peptide sequence Pro-Pro-Asp-Lys.

Graphical abstract: Bioorganic hybrid OMS by straightforward grafting of trialkoxysilyl peptides

Supplementary files

Article information

Article type
Paper
Submitted
25 Jan 2013
Accepted
17 Apr 2013
First published
17 Apr 2013

J. Mater. Chem. B, 2013,1, 2921-2925

Bioorganic hybrid OMS by straightforward grafting of trialkoxysilyl peptides

S. Jebors, C. Enjalbal, M. Amblard, A. Mehdi, G. Subra and J. Martinez, J. Mater. Chem. B, 2013, 1, 2921 DOI: 10.1039/C3TB20122H

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