An octanuclear {CuII4DyIII4} coordination cluster showing single molecule magnet behaviour from field accessible states

Irina A. Kühne; Nicola Magnani; Valeriu Mereacre; Wolfgang Wernsdorfer; Christopher E. Anson; Annie K. Powell

doi:10.1039/C3CC46458J

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An octanuclear {Cu^II₄Dy^III₄} coordination cluster showing single molecule magnet behaviour from field accessible states†

Irina A. Kühne,^a Nicola Magnani,^b Valeriu Mereacre,^a Wolfgang Wernsdorfer,^c Christopher E. Anson^a and Annie K. Powell*^ab

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesser Str. 15, Karlsruhe, Germany
E-mail: annie.powell@kit.edu
Fax: +49 721-608-8142

^b Institute of Nanotechnology, Karlsruhe Institute of Technology, Postfach 3640, Karlsruhe, Germany

^c Institut Néel, CNRS, Nanoscience Department, BP 166, 380412 Grenoble Cedex 9, France

Abstract

The structure and magnetic properties of an octanuclear coordination cluster with a {Cu^II₄Dy^III₄} core are described and a model for the unusual SMM behaviour is proposed.

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Article information

DOI: https://doi.org/10.1039/C3CC46458J
Article type: Communication
Submitted: 23 Aug 2013
Accepted: 20 Nov 2013
First published: 21 Nov 2013

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Chem. Commun., 2014,50, 1882-1885

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An octanuclear {Cu^II₄Dy^III₄} coordination cluster showing single molecule magnet behaviour from field accessible states

I. A. Kühne, N. Magnani, V. Mereacre, W. Wernsdorfer, C. E. Anson and A. K. Powell, Chem. Commun., 2014, 50, 1882 DOI: 10.1039/C3CC46458J

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