Issue 2, 2014
From the journal:

Chemical Communications

Enantioselective organocatalytic oxidative enamine catalysis–1,5-hydride transfer–cyclization sequences: asymmetric synthesis of tetrahydroquinolines†

Young Ku Kanga  and  Dae Young Kim*a  

* Corresponding authors

a Department of Chemistry, Soonchunhyang University, 22 Soonchunhyang-Ro, Asan, Chungnam 336-745, Korea
E-mail: dyoung@sch.ac.kr
Fax: +82-41-530-1247
Tel: +82-41-530-1244

Abstract

The first organocatalytic enantioselective intramolecular oxidative enamine catalysis and 1,5-hydride transfer–ring closure reaction cascade is described. This neutral reaction cascade allows for the efficient formation of ring-fused tetrahydroquinolines with high enantioselectivities.

Graphical abstract: Enantioselective organocatalytic oxidative enamine catalysis–1,5-hydride transfer–cyclization sequences: asymmetric synthesis of tetrahydroquinolines

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Article information

DOI
https://doi.org/10.1039/C3CC46710D
Article type
Communication
Submitted
03 Sep 2013
Accepted
25 Oct 2013
First published
25 Oct 2013

Chem. Commun., 2014,50, 222-224

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Enantioselective organocatalytic oxidative enamine catalysis–1,5-hydride transfer–cyclization sequences: asymmetric synthesis of tetrahydroquinolines

Y. K. Kang and D. Y. Kim, Chem. Commun., 2014, 50, 222 DOI: 10.1039/C3CC46710D

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