Intramolecular electron transfer between molybdenum and iron mimicking bacterial sulphite dehydrogenase†
Abstract
Diferrocenyl/diferrocenium substituted dioxido molybdenum(VI) complexes [Fe2MoO2] 2Fc/[2Fc]2+ mimic the catalytic active site including the redox subunits as well as the catalytic function of bacterial sulphite oxidases.