Iron(III) sulfate, a rhombohedral NASICON compound, has been demonstrated as a sodium intercalation host. This cost-effective material is attractive, as it can be slurry processed in bulk with ball-milling, while utilizing the iron 2+/3+ redox couple, offering stable 3.2 V performance for over 400 cycles.
C. W. Mason, I. Gocheva, H. E. Hoster and D. Y. W. Yu, Chem. Commun., 2014, 50, 2249 DOI: 10.1039/C3CC47557C
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