The luminescence properties of linear vs. kinked aurophilic 1-D chains of bis(dithiocarbamato)gold(i) dimers†
Abstract
Widely varying luminescence spectra are reported for 1-D chains of bis(dithiocarbamato)gold(I) dimers. Variable pressure luminescence spectra elucidate the effect of angular overlap on the emission properties of the aurophilic chain.