Multifarenes, a new class of macrocycles, which are constructed of alternating building blocks, are conveniently accessible by three complementary syntheses that provide modularity and scalability. In addition to metal-ion coordination, these cavitands show increased flexibility with increasing ring size, offering opportunities for induced fit to guest molecules.
G. Parvari, S. Annamalai, I. Borovoi, H. Chechik, M. Botoshansky, D. Pappo and E. Keinan, Chem. Commun., 2014, 50, 2494 DOI: 10.1039/C3CC48284G
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