The peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkoxy vinylsilanes leads to functionalized trialkoxysilanes. Prior addition of the dithiocarbonates to an alkene before reaction with the vinylsilane can be used to increase the complexity of the final product.
B. Quiclet-Sire, Y. Yanagisawa and S. Z. Zard, Chem. Commun., 2014, 50, 2324 DOI: 10.1039/C3CC48570F
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