A new chiral iron porphyrin-based catalyst performed α-methylstyrene stereoselective cyclopropanation with excellent yields (up to 99%), enantio- and diastereoselectivities (eetrans up to 87%, trans/cis ratios up to 99 : 1) and outstanding TON and TOF values (up to 20 000 and 120 000 h−1 respectively).
D. Intrieri, S. Le Gac, A. Caselli, E. Rose, B. Boitrel and E. Gallo, Chem. Commun., 2014, 50, 1811 DOI: 10.1039/C3CC48605B
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