Issue 21, 2014
From the journal:

Chemical Communications

Oxidation of 2-amino-substituted BODIPYs providing pyrazine-fused BODIPY trimers†

Hiroki Yokoi,a   Naruhiko Wachi,a   Satoru Hiroto*a  and  Hiroshi Shinokubo*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan
E-mail: hitoro@apchem.nagoya-u.ac.jp, hshino@apchem.nagoya-u.ac.jp
Fax: +81-52-789-3188

Abstract

Oxidation of 2-amino-substituted BODIPYs afforded BODIPY trimers in a one-step operation. The trimer consists of a pyrazine-fused BODIPY dimer to which one BODIPY unit is connected through an NH linkage. Effective expansion of π-conjugation over the fused dimer was observed in optical and electrochemical measurements.

Graphical abstract: Oxidation of 2-amino-substituted BODIPYs providing pyrazine-fused BODIPY trimers

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Article information

DOI
https://doi.org/10.1039/C3CC48738E
Article type
Communication
Submitted
15 Nov 2013
Accepted
11 Dec 2013
First published
12 Dec 2013

Chem. Commun., 2014,50, 2715-2717

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Oxidation of 2-amino-substituted BODIPYs providing pyrazine-fused BODIPY trimers

H. Yokoi, N. Wachi, S. Hiroto and H. Shinokubo, Chem. Commun., 2014, 50, 2715 DOI: 10.1039/C3CC48738E

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