Issue 14, 2014
From the journal:

Chemical Communications

An isoelectronic NO dioxygenase reaction using a nonheme iron(iii)-peroxo complex and nitrosonium ion†

Atsutoshi Yokoyama,a   Jung Eun Han,a   Kenneth D. Karlin*b  and  Wonwoo Nam*a  

* Corresponding authors

a Department of Chemistry and Nano Science, Department of Bioinspired Science, Ewha Womans University, Seoul 120-750, Korea
E-mail: wwnam@ewha.ac.kr
Fax: +82-2-3277-4441
Tel: +82-2-3277-2392

b Department of Chemistry, The Johns Hopkins University, Baltimore, MD 21218, USA
E-mail: karlin@jhu.edu

Abstract

Reaction of a nonheme iron(III)-peroxo complex, [FeIII(14-TMC)(O2)]+, with NO+, a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O2˙−) + NO], affords an iron(IV)-oxo complex, [FeIV(14-TMC)(O)]2+, and nitrogen dioxide (NO2), followed by conversion to an iron(III)-nitrato complex, [FeIII(14-TMC)(NO3)(F)]+.

Graphical abstract: An isoelectronic NO dioxygenase reaction using a nonheme iron(iii)-peroxo complex and nitrosonium ion

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Article information

DOI
https://doi.org/10.1039/C3CC48782B
Article type
Communication
Submitted
18 Nov 2013
Accepted
11 Dec 2013
First published
13 Dec 2013

Chem. Commun., 2014,50, 1742-1744

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An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion

A. Yokoyama, J. E. Han, K. D. Karlin and W. Nam, Chem. Commun., 2014, 50, 1742 DOI: 10.1039/C3CC48782B

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