Issue 14, 2014
From the journal:

Chemical Communications

Beyond the anisotropy barrier: slow relaxation of the magnetization in both easy-axis and easy-plane Ln(trensal) complexes†

Eva Lucaccini,a   Lorenzo Sorace,*a   Mauro Perfetti,a   Jean-Pierre Costesb  and  Roberta Sessolia  

* Corresponding authors

a Dipartimento di Chimica “U. Schiff” and UdR INSTM, Universitá di Firenze, Via della Lastruccia 3-13, Sesto Fiorentino(FI), Italy
E-mail: lorenzo.sorace@unifi.it
Fax: +39 0554573372
Tel: +39 0554573336

b Laboratoire de Chimie de Coordination 205, route de Narbonne 31077 Toulouse, Cedex 4, France

Abstract

We present a spectroscopic and magnetic (both static and dynamic) characterization of two isostructural Dy and Er complexes evidencing that, despite the different types of magnetic anisotropy, the two molecules show similar slow relaxation of the magnetization in a static magnetic field.

Graphical abstract: Beyond the anisotropy barrier: slow relaxation of the magnetization in both easy-axis and easy-plane Ln(trensal) complexes

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Article information

DOI
https://doi.org/10.1039/C3CC48866G
Article type
Communication
Submitted
20 Nov 2013
Accepted
05 Dec 2013
First published
06 Dec 2013

Chem. Commun., 2014,50, 1648-1651

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Beyond the anisotropy barrier: slow relaxation of the magnetization in both easy-axis and easy-plane Ln(trensal) complexes

E. Lucaccini, L. Sorace, M. Perfetti, J. Costes and R. Sessoli, Chem. Commun., 2014, 50, 1648 DOI: 10.1039/C3CC48866G

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