Issue 31, 2014
From the journal:

Chemical Communications

A chiral spin crossover metal–organic framework†

Wei Liu,a   Xin Bao,b   Ling-Ling Mao,a   Jiri Tucek,c   Radek Zboril,c   Jun-Liang Liu,a   Fu-Sheng Guo,a   Zhao-Ping Nia  and  Ming-Liang Tong*a  

* Corresponding authors

a School of Chemistry & Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, P. R. China
E-mail: tongml@mail.sysu.edu.cn

b Department of Chemistry, School of Chemical Engineering, Nanjing University of Science and Technology, 210094 Nanjing, P. R. China

c Regional Centre of Advanced Technologies and Materials, Department of Experimental Physics, Faculty of Science, Palacky University, Slechtitelu 11, 783 71 Olomouc, Czech Republic

Abstract

A chiral metal–organic framework exhibiting spin crossover (SCO) property, [FeII(mptpy)2]·EtOH·0.2DMF (1·solv), has been solvothermally synthesized through spontaneous resolution. It displays remarkable stability and two-step SCO at (Tc1 = 200 K) and above (Tc2 = 357 K) room temperature.

Graphical abstract: A chiral spin crossover metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C3CC48935C
Article type
Communication
Submitted
22 Nov 2013
Accepted
21 Feb 2014
First published
21 Feb 2014

Chem. Commun., 2014,50, 4059-4061

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A chiral spin crossover metal–organic framework

W. Liu, X. Bao, L. Mao, J. Tucek, R. Zboril, J. Liu, F. Guo, Z. Ni and M. Tong, Chem. Commun., 2014, 50, 4059 DOI: 10.1039/C3CC48935C

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