Issue 22, 2014
From the journal:

Chemical Communications

Observation of allylic rearrangement in water-rich reaction†

Yuan-Chao Pang,‡a   Xiufang Hou,‡a   Lei Qin,a   Chao Wu,*a   Wei Xue,b   Yan-Zhen Zheng,*a   Zhiping Zhenga  and  Xiao-Ming Chenb  

* Corresponding authors

a Frontier Institute of Science and Technology, and College of Science, Xi'an Jiaotong University, Xi'an 710054, China
E-mail: zheng.yanzhen@mail.xjtu.edu.cn, chaowu@mail.xjtu.edu.cn

b School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China

Abstract

Allylic rearrangement or the migration of a double bond from its original position in the carbon skeleton to an adjacent site was observed when 3,4,5,6-tetrahydrophthalate was hydrolyzed in a basic solution and in the presence of Co(II) and Mn(II) under hydrothermal conditions.

Graphical abstract: Observation of allylic rearrangement in water-rich reaction

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Article information

DOI
https://doi.org/10.1039/C3CC49287G
Article type
Communication
Submitted
06 Dec 2013
Accepted
23 Jan 2014
First published
24 Jan 2014

Chem. Commun., 2014,50, 2910-2912

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Observation of allylic rearrangement in water-rich reaction

Y. Pang, X. Hou, L. Qin, C. Wu, W. Xue, Y. Zheng, Z. Zheng and X. Chen, Chem. Commun., 2014, 50, 2910 DOI: 10.1039/C3CC49287G

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