Issue 28, 2014
From the journal:

Chemical Communications

Unprecedented non-aromatic, conformationally locked dibenzohexaphyrin analogs carrying multiple meso-exocyclic double bonds†

Dowoo Park,a   Na Young Choi,a   Seong-Jin Honga  and  Chang-Hee Lee*a  

* Corresponding authors

a Department of Chemistry and Institute of Molecular Science & Fusion technology, Kangwon National University, Chun-Chon 200-701, Korea
E-mail: chhlee@kangwon.ac.kr

Abstract

Acid-catalysed, ‘3+3’ condensation of m-bispyrryl benzene derivatives with acetone afforded new non-aromatic macrocycles that can be converted to meso-alkylidenyl dibenzohexaphyrins carrying four exocyclic double bonds at meso-positions by DDQ oxidation.

Graphical abstract: Unprecedented non-aromatic, conformationally locked dibenzohexaphyrin analogs carrying multiple meso-exocyclic double bonds

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Article information

DOI
https://doi.org/10.1039/C3CC49380F
Article type
Communication
Submitted
10 Dec 2013
Accepted
12 Feb 2014
First published
13 Feb 2014

Chem. Commun., 2014,50, 3689-3691

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Unprecedented non-aromatic, conformationally locked dibenzohexaphyrin analogs carrying multiple meso-exocyclic double bonds

D. Park, N. Y. Choi, S. Hong and C. Lee, Chem. Commun., 2014, 50, 3689 DOI: 10.1039/C3CC49380F

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