Preparation and structure of acenaphthylene-1,2-diyldi(9-acridine) derivatives with a long CC bond

Takashi Takeda; Yasuto Uchimura; Hidetoshi Kawai; Ryo Katoono; Kenshu Fujiwara; Takanori Suzuki

doi:10.1039/C3CC49573F

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Preparation and structure of acenaphthylene-1,2-diyldi(9-acridine) derivatives with a long CC bond†

Takashi Takeda,*^a Yasuto Uchimura,^b Hidetoshi Kawai,^c Ryo Katoono,^b Kenshu Fujiwara^b and Takanori Suzuki*^b

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* Corresponding authors

^a Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai, Miyagi 980-8577, Japan
E-mail: takeda@tagen.tohoku.ac.jp
Fax: +81-22-217-5654
Tel: +81-22-217-5655

^b Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo, Hokkaido 060-0810, Japan
E-mail: tak@mail.sci.hokudai.ac.jp
Fax: +81-11-706-2714
Tel: +81-11-706-2714

^c Department of Chemistry, Faculty of Science, Tokyo University of Science, Shinjuku, Tokyo 162-8601, Japan

Abstract

Due to purely steric effects of acridine units, acenaphthylene-1,2-diyldi(9-acridine) has a long C [double bond, length as m-dash] C bond [1.3789(19) Å] while maintaining its sp² hybridized nature and bond order.

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DOI: https://doi.org/10.1039/C3CC49573F
Article type: Communication
Submitted: 18 Dec 2013
Accepted: 19 Jan 2014
First published: 20 Jan 2014
This article is Open Access

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Chem. Commun., 2014,50, 3924-3927

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Preparation and structure of acenaphthylene-1,2-diyldi(9-acridine) derivatives with a long CC bond

T. Takeda, Y. Uchimura, H. Kawai, R. Katoono, K. Fujiwara and T. Suzuki, Chem. Commun., 2014, 50, 3924 DOI: 10.1039/C3CC49573F

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Chemical Communications

Preparation and structure of acenaphthylene-1,2-diyldi(9-acridine) derivatives with a long CC bond†

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Preparation and structure of acenaphthylene-1,2-diyldi(9-acridine) derivatives with a long CC bond

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