A simple and rapid access to the α-substituted acryl aldehydes has been provided by developing a gold-catalysed [1,3] rearrangement of the allenyl ethers importantly with a record turnover frequency of 4600 h−1 (at 0.05 mol% of the catalyst concentration) in homogeneous gold(I) catalysis.
![Graphical abstract: Gold(i)-catalysed [1,3] O→C rearrangement of allenyl ethers](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C3CC49629E&imageInfo.ImageIdentifier.Year=2014)
C. N. Kona and C. V. Ramana, Chem. Commun., 2014, 50, 2152 DOI: 10.1039/C3CC49629E
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