Issue 24, 2014
From the journal:

Chemical Communications

Single-crystal-to-single-crystal transformation of a two-dimensional coordination polymer through highly selective [2+2] photodimerization of a conjugated dialkene†

Dong Liu,ab   Hui-Fang Wang,a   Brendan F. Abrahamsc  and  Jian-Ping Lang*a  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China
E-mail: jplang@suda.edu.cn
Fax: +86-512-65880089

b College of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, P. R. China

c School of Chemistry, University of Melbourne, Victoria 3010, Australia

Abstract

A 2D network [Zn4(OH)2(5-NO2-1,3-BDC)2(5-NO2-1,3-HBDC)2(ppene)2]n underwent a highly selective [2+2] photodimerization reaction upon UV irradiation. The coordination polymer retains its single crystallinity after photoreaction.

Graphical abstract: Single-crystal-to-single-crystal transformation of a two-dimensional coordination polymer through highly selective [2+2] photodimerization of a conjugated dialkene

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Article information

DOI
https://doi.org/10.1039/C3CC49749F
Article type
Communication
Submitted
24 Dec 2013
Accepted
02 Feb 2014
First published
03 Feb 2014

Chem. Commun., 2014,50, 3173-3175

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Single-crystal-to-single-crystal transformation of a two-dimensional coordination polymer through highly selective [2+2] photodimerization of a conjugated dialkene

D. Liu, H. Wang, B. F. Abrahams and J. Lang, Chem. Commun., 2014, 50, 3173 DOI: 10.1039/C3CC49749F

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