Polymorphism of metal–organic frameworks: direct comparison of structures and theoretical N2-uptake of topological pto- and tbo-isomers

Nianyong Zhu; Matthew J. Lennox; Tina Düren; Wolfgang Schmitt

doi:10.1039/C3CC49829H

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Polymorphism of metal–organic frameworks: direct comparison of structures and theoretical N₂-uptake of topological pto- and tbo-isomers†

Nianyong Zhu,^a Matthew J. Lennox,^b Tina Düren^b and Wolfgang Schmitt*^a

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* Corresponding authors

^a School of Chemistry & CRANN, University of Dublin, Trinity College, Dublin 2, Ireland
E-mail: schmittw@tcd.ie
Tel: +353-1-896-3495

^b Institute for Materials and Processes, School of Engineering, The University of Edinburgh, Mayfield Road, Edinburgh, EH9 3JL, UK

Abstract

The syntheses, calculated surface areas and N₂ uptakes of two highly augmented {Cu}₂ ‘paddlewheel’-based MOFs provide a direct comparison of tbo and pto framework polymorphs with identical composition.

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Article information

DOI: https://doi.org/10.1039/C3CC49829H
Article type: Communication
Submitted: 30 Dec 2013
Accepted: 24 Feb 2014
First published: 25 Feb 2014

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Chem. Commun., 2014,50, 4207-4210

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Polymorphism of metal–organic frameworks: direct comparison of structures and theoretical N₂-uptake of topological pto- and tbo-isomers

N. Zhu, M. J. Lennox, T. Düren and W. Schmitt, Chem. Commun., 2014, 50, 4207 DOI: 10.1039/C3CC49829H

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