Issue 23, 2014
From the journal:

Chemical Communications

Control of the conformational dynamics of meso–meso vinylene-bridged Zn(ii) porphyrin dimers through diamine coordination†

Minjung Son,a   Young Mo Sung,a   Sumito Tokuji,b   Norihito Fukui,b   Hideki Yorimitsu,b   Atsuhiro Osuka*b  and  Dongho Kim*a  

* Corresponding authors

a Department of Chemistry, Yonsei University, Seoul 120-749, Korea
E-mail: dongho@yonsei.ac.kr
Fax: +82 2-2123-2434
Tel: +82 2-2123-2652

b Department of Chemistry and Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan
E-mail: osuka@kuchem.kyoto-u.ac.jp
Fax: +81-75-753-3970
Tel: +81-75-753-4008

Abstract

Two meso–meso vinylene-bridged Zn(II) porphyrin dimers 1 and 2 were analyzed in terms of the control of their conformational dynamics induced by the rotation around the double bond bridge. The dihedral angles between the two porphyrin rings were modulated through coordination with α,ω-diaminoalkanes of varying chain lengths.

Graphical abstract: Control of the conformational dynamics of meso–meso vinylene-bridged Zn(ii) porphyrin dimers through diamine coordination

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Article information

DOI
https://doi.org/10.1039/C4CC00126E
Article type
Communication
Submitted
07 Jan 2014
Accepted
03 Feb 2014
First published
04 Feb 2014

Chem. Commun., 2014,50, 3078-3080

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Control of the conformational dynamics of meso–meso vinylene-bridged Zn(II) porphyrin dimers through diamine coordination

M. Son, Y. M. Sung, S. Tokuji, N. Fukui, H. Yorimitsu, A. Osuka and D. Kim, Chem. Commun., 2014, 50, 3078 DOI: 10.1039/C4CC00126E

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