The recently developed CLSA-NMR technique that is based on feeding experiments with 13C-labelled precursors was applied in the identification of isoafricanol as the main volatile terpene emitted by Streptomyces violaceusniger. The isoafricanol synthase of this organism is presented, together with a recent phylogenetic analysis of bacterial terpene cyclases.
R. Riclea, C. A. Citron, J. Rinkel and J. S. Dickschat, Chem. Commun., 2014, 50, 4228 DOI: 10.1039/C4CC00177J
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