A straightforward synthesis of P-chiral polycyclic 7-phospha-norbornenes via an asymmetric Diels–Alder reaction is presented. The employed starting materials are cheap, easily accessible and of structural diversity facilitating a new flexible route towards differently functionalised P-chiral phosphanes.
T. Möller, P. Wonneberger, N. Kretzschmar and E. Hey-Hawkins, Chem. Commun., 2014, 50, 5826 DOI: 10.1039/C4CC00318G
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