Issue 31, 2014
From the journal:

Chemical Communications

Stereospecific hydrodehalogenation of alkenyl bromides: a new approach to the synthesis of (E)-alkenes†

Giorgio Cheluccia  

a Dipartimento di Agraria, Università di Sassari, viale Italia 39, I-07100 Sassari, Italy
E-mail: chelucci@uniss.it
Fax: +39-079-229559
Tel: +39-079-229539

Abstract

The pair NaBH4–TMEDA and catalytic PdCl2(PPh3)2 in THF at room temperature is a mild and efficient system for the hydrodebromination of alkenyl bromides, providing a facile reduction procedure that allows completing the process advantageously, leading from aldehydes to (E)-alkenes.

Graphical abstract: Stereospecific hydrodehalogenation of alkenyl bromides: a new approach to the synthesis of (E)-alkenes

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Article information

DOI
https://doi.org/10.1039/C4CC00345D
Article type
Communication
Submitted
15 Jan 2014
Accepted
17 Feb 2014
First published
17 Feb 2014

Chem. Commun., 2014,50, 4069-4072

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Stereospecific hydrodehalogenation of alkenyl bromides: a new approach to the synthesis of (E)-alkenes

G. Chelucci, Chem. Commun., 2014, 50, 4069 DOI: 10.1039/C4CC00345D

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